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item de pka


Go to solution Solved by Magnum,

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  • Ancien Responsable Matière
Posted

Re ^^

QCM 8 : Soit une solution aqueuse d'un monoacide de molarité m=0,1 présentant un pH=4 :

--> . Le pKa de ce monoacide est égal à 7 VRAI

 

j'ai utilisé la formule ph = 1/2 (pka - logm)

donc pka = (ph + 1/2logm) / 1/2 

pka = (ph + 1/2 log m) *2

pka = (4 + 1/2 log0,1)*2

pka = (4 + 1/2 *1)*2 = 4,5*2 = 9 ???

 

Où se trouve mon erreur ?

  • Solution
Posted

Salut solenfdo! 

Attention tu as oublié ton 1/2!
pH = 1/2 pka - 1/2 logm

--> 1/2pka = pH + 1/2 logm

--> 1/2pka = 4 + (1/2 x -1)
--> 1/2 pka = 4 - 0,5
--> 1/2 pka = 3,5 --> *2
--> pka = 7 ? 

  • Ancien Responsable Matière
Posted

Aaaaaah ok merci @Magnum !! (j'avais oublié le - aussi ^^'''') merci beaucoup génial tu gères ? 

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