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CCB RANGUEIL 2015 - QCM 18


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re championne !

 

alors on a : E = E° + 0,06/n *log(Ox/Red) , cette formule concerne 1 seul couple (

 

Ici on nous demande ΔE, soit ΔE = E1 - E2 (avec E1 > E2) soit ΔE = ( E° + 0,06/n *log(Ox/Red) )1 - ( E° + 0,06/n *log(Ox/Red) )2

 

 

Commençons par E1 : avec le couple Ce4+/Ce3+, on a donc E1 = 1,44 + 0,06/1 *log(10^-2/10^-4) = 1,44 + 0,06*log(10^2) = 1,44 + 0,06*2 = 1,56V

 

Poursuivons par E2 : avec le couple Fe3+/Fe2+, on a donc E1 = 0,77 + 0,06/1 *log(10^-2/10^-4) = 0,77 + 0,06*log(10^2) = 0,77 + 0,06*2 = 0,89V

 

 

DONC E1 - E2 = 1,56 - 0,89 = 0,67V

 

 

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